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June 2009

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Subject:
From:
"Wenger, George M." <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Wenger, George M.
Date:
Fri, 12 Jun 2009 13:28:35 -0400
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text/plain
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text/plain (190 lines)
Solder mask defined pads or non-so
Electrolytic Ni-Au or ENIG?



Solder mask defined pads or non-solder mask defined pads?



Has any ionic contamination measurement been done of the PCB before assembly?



All of the above questions are asked to determine if there is any plating chemistry trapped that isn't cleaned off before assembly.



However, when the customer indicates they don't see the Sn migration with SnPb assembly I'd go back to your statement earlier about the flux-vehicle in the SAC solder paste is most likely different than for the SnPb paste and has to be considered a suspect.



Regards,

George

George M. Wenger

Andrew Solutions

Senior Principal FMA / Reliability Engineer

40 Technology Drive, Warren, NJ 07059

(908) 546-4531 [Office]  (732) 309-8964 [Cell]

[log in to unmask]

 



-----Original Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Karen Tellefsen

Sent: Friday, June 12, 2009 1:19 PM

To: [log in to unmask]

Subject: Re: [TN] Strange tin "migration" under OFN soldered with no-clean SAC305 solder paste



More information from our tech service engineer:



      There is no hand soldering.

      The board is Ni-Au

      The boards are clean... no issue with Sn Pb



Could it be galvanic corrosion with exposed Ni or Au acting as a cathode,

allowing the tin in the solder joint to corrode?  Maybe there is some metal

surface on the QFN that can act as a cathode.



There's no externally applied voltage, maybe there is a battery somewhere

on the board.







Karen Tellefsen - Electrical Testing

[log in to unmask]

908-791-3069



Dave Hillman wrote:



Hi Karen - you should attempt to determine if any  ionic contamination is

present - you could just have a typical electrochemical migration issue to

due contamination.



Dave Hillman

Rockwell Collins

[log in to unmask]









Karen Tellefsen <[log in to unmask]>

Sent by: TechNet <[log in to unmask]>

06/12/2009 11:12 AM

Please respond to

TechNet E-Mail Forum <[log in to unmask]>; Please respond to

Karen Tellefsen <[log in to unmask]>





To

[log in to unmask]

cc



Subject

Re: [TN] Strange tin "migration" under OFN soldered with no-clean SAC305

solder paste













I'm not sure; I'm getting my information second hand.



Thanks



-------------------

Karen,



Are you sure this is migration? They might very well be plain shorts from

excess of solder or manual component realignment before reflow. Has the

assembler checked the components under X-Ray before the conditioning, just

to make sure everything is clean at the exit of the oven?



Just a thought,



Ioan Tempea, ing.

t : 450-967-7100 ext : 244

[log in to unmask]

www.digico.cc

P N'imprimer que si nécessaire - Print only if you must



----- Forwarded by Karen Tellefsen/AlphaMetalsUS/Cookson on 06/12/2009

10:47 AM -----



             Karen

             Tellefsen/AlphaMe

             talsUS/Cookson                                             To

                                       [log in to unmask]

             06/12/2009 10:26                                           cc

             AM

                                                                   Subject

                                       Strange tin "migration" under OFN

                                       soldered with no-clean SAC305

                                       solder paste



















One of our technical service engineers asked me about a strange migration

phenomenon one of our customers observed under passives and QFN's that

have

been soldered with one of our no-clean SAC305 solder pastes. I've attached

an X-ray picture of a QFN exhibiting this strange failure, but I don't

know

how it can be posted so you can look at it.. Further analysis after

removing the component showed that the shadows in the X-ray picture is

caused by a black material containing tin. The boards were conditioned

85°C

85%RH  for 500 hr, but no voltage was applied.  This phenomenon was not

observed under QFPs (not surprising), and seems to be independent of

reflow

profile used.  Additionally, the customer has not seen anything like this

with tin lead solder paste, however, the tin-lead solder pastes would have

a different fluxes.   The tin "migration" is coming from both adjacent

solder joints, and there is no voltage applied, so it seems to be a

corrosion problem.  Certainly QFN and big passives are good at trapping

and

retaining water in the flux residue underneath them.



I've never seen anything like this; has anyone else out in TechNet land

seen this or have any ideas what caused this?



Thanks



Karen Tellefsen - Electrical Testing

[log in to unmask]









Enthone GmbH  Geschäftsführer: Knut Balzer, Luc de Croo, Jürgen Dietrich  Amtsgericht Düsseldorf  HRB 45276

USt-Id-Nr. DE 811 205 946 





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