Hi Ziyi -

Please note the pollowing points about Cr+6:

1. Testing by XRF should only be doine as an audit mechanism since the 
accuracy is inferior to spectrascopy. All test for certification to 
customers should be by spectrascopy ir some may reject or challange the 
report.

2. The main use of Cr+6 in electronics is as "Chromate" coating of metals 
and pigment (colorant) in inks, paints and plastics.

3. Some OEMs are requiring more strict limits for Cr+6 and Cd. I suggest 
to check your customer's specifications carefully, especially Japanese 
customers or OEMs of monile phones. In this case "Green" requirements may 
exceed RoHS.

Regards,

C.B. Katzko, CTO
Meadville Group
e-mail  [log in to unmask]
tel            +86 21 3774 7528
fax           +86 21 3774 7590
mobile   +86 13817362590

+++  Please note new tel & fax numbers.  +++



Benjamin Chen <[log in to unmask]> 
发件人:  TGAsia <[log in to unmask]>
2008-01-02 17:31
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Re: [TGA] RoHS管制+6价的Cr,为何是离子态的管 制?







Hi Ziyi, 

As the supplementary information for other's answers. 

It is because the Cr6+ is more toxic than Cr or Cr3+, but its existence in 
nature is by chemical compound in solid state with other ions or ionic 
groups.  The analysis is to measure how much of chromium existed as the 
state of Cr6+ in the chemical compounds of the product.  Though existed in 
chemical compound state (solid), when inhaled or other ways into human 
bodies, it will be then decomposed into Cr6+ in human body (as the salt 
dissolved in blood or water) to cause toxic reaction.  How we verify the 
existence of Cr6+ is usually by X-Ray Fluorescence (nondestructive), 
UV-Visible Spectroscopy (destructive) quantitatively, or other known 
chemical reactions quantitatively or qualitatively.

Hope this helps, and please feel free to let me know if any further 
information necessary, thank you very much!!

xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx

Benjamin Chen
Regional Technical Coordinator, Asia-Pacific
Consulting and Training
Underwriters Laboratories Taiwan Co., Ltd.
Tel: 886-2-2896-7790 ext. 62267, Fax: 886-2-2896-6140
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- Know by test, and state the facts. -
Web site: http://www.UL.com.tw 


Ziyi Li <[log in to unmask]> 
Sent by: TGAsia <[log in to unmask]> 
01/02/2008 04:59 PM 

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Subject
[TGA] RoHS管制+6价的Cr,为何是离子态的管制?









Dear All: 
   为什么RoHS管制+6价的Cr?在我认为:固态的产品(电镀层)如何出现离子态,很
另人困惑~,恳请各位支招! 
谢谢! 
Best Regards 
************************************************
支架事业处 工程&品管 课长 李子祎
扬州华夏集成光电有限公司 
地址:江苏扬州经济开发区扬子江南路518号(邮编:225009) 
网址:http://www.darewinchip.com 
邮箱:[log in to unmask] 
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传真:0514-87849312
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