George!
 
I did not refer to the traditional form of gold embrittlement. There are numerous papers showing that gold may cause a new form of embrittlement when soldering to nickel surfaces. After soldering the gold will be find as AuSn intermetallic compounds evenly dispersed in the solder joint. However, after some time, that is no longer the case. Most of the gold will be found in a layer of AuNiSn IMC that is formed on top of the NiSn IMC layer on the nickel surface, which cause an embrittlement of the solder joint. The higher the temperature, the faster this will happen. At 150 degree C, you may have an ebrittlement of the solder joint after 24 hours and it might happen if the gold concentration is higher than 0.3 % and it is likely that you get that if you have a plating with electrolytic nickel/electrolytic gold on the component solder lands.
 
For more information, se the following references:

A. Eslambolchi, P. Johnson, M. Kaufmann och Z. Mei, Electroless Ni/Immersion Au Evaluation – Final Program Report, Electronic Assembly Development Center, Hewlett-Packard, Palo Alto, 1998.

K. Zeng och K.N. Tu, Six Cases of Reliability Study of Pb-free Solder Joints in Electronic Packaging Technology, Materials Science and Engineering R, Vol. 38, 2002, sida 55-105.

A. Zribi, R.R. Chromik, R. Presthus, K. Teed, L. Zavalij, J. DeVita, J. Tova, E.J. Cotts, J.A. Clum, R. Erich, A. Primavera, G. Westby, R.J. Coyle och G.M. Wenger, Solder Metallization Interdiffusion in Microelectronic Interconnects, IEEE Trans. on Comp. and Pack. Techn. Vol. 23, Nr. 2, 2000, sida 383-387.

R. Darveaux, K. Banerji, A. Mawer och G. Dody, Reliability of Plastic Ball Grid Array Assembly, J.H. Lau (Ed.), Ball Grid Array Technology, McGraw-Hill, Inc., 1995, Kapitel 13.

A.M Minor och J.W. Morris, Jr., Growth of Au-Ni-Sn Intermetallic Compound on the Solder-Substrate Interface After Aging, Metall. Mater. Trans, A, 31A, 2000, p. 789. http://www.lbl.gov/morris/private/papers.html

A.M. Minor och J.W. Morris, Inhibiting Growth of the Au0.5Ni0.5Sn4 Intermetallic Layer in Pb-Sn Solder Joints Reflowed on Au/Ni Metallization, Journal of Electronic Materials, October 2000, Vol. 29, Issue 10, sida 1170-1174. http://www.lbl.gov/morris/private/papers.html
 
Per-Erik Tegehall
IVF, Sweden
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Från: George Milad [mailto:[log in to unmask]]
Skickat: den 14 oktober 2003 04:45
Till: [log in to unmask]
Ämne: Re: [TN] ENIG solder joint embrittlement

The firgure reported by Glazer from Hp for gold embrittlement was 3% and not 0.3%. The total amount of gold in ENIG if the new IPC 4552 specification is followed is less than 5 micro-inches or 0.12 microns.
If one does the math, then it is evident that under these conditions "Solder Joint Gold  Embrittlement" is a non issue for ENIG.
Of course this is all on the board side and not the component. If there is an issue with component side separation, the target investigation should not be on ENIG leaving the true cause unidentified or addressed.
Blaming the ENIG finish idiscrimanetly, and using the "black Pad" as a catch all leaves a lot of areas, where things could go wrong, unidentified and more important not corrected.
Blaming the "Black pad" is prevalent. I often wonder how prevalent the ture cases of "Black Pad" are?

George Milad
Uyemura International Corp
Chairman IPC Plating Commitee
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