The presence of lead in the joint allows for the theoretical possibility of
the Sn/Pb/Ag eutectic forming. This has a solidus of 179C  [The liquidus of
the solder will still be >220C]
If this Pb is washing off your boards/components, there is a real
possibility of a locally high concentration of Sn/PB and therefore of a
depressed Sn content in the adjacent area leaving a surplus of ...it begins
to be hard to forecast everything. Whatever there is the distinct
possibility of a different strength/composition/flexibility layer in the
solder joint. This discontinuity would be visible in micrographic section
and is undesirable from a reliability point of view.

You may also be seeing effects of this in terms of surface appearance  -
slight frostiness - although probably joint shape and wetting etc are not
[yet] effected.

In a perfect world you solder lead free components with your Sn/Ag solder,
in a real world you have an analysis program so you can monitor these
increases and take corrective action. The only thing which puzzles me is the
amount - 1% represents a lot of devices and I would have thought regular
drag out and replenishment would not normally allow this build up. Perhaps
you have a nearby Sn63 machine?


Regards
Mike Fenner

Applications Engineer, European Operations
Indium Corporation
 T: + 44 1908 580 400
M: + 44 7810 526 317
 F: + 44 1908 580 411
 E: [log in to unmask]
W: www.indium.com
Leadfree: www.Pb-Free.com

  -----Original Message-----
  From: TechNet [mailto:[log in to unmask]]On Behalf Of Stolar, Paul W
  Sent: Tuesday, January 14, 2003 9:49 PM
  To: [log in to unmask]
  Subject: [TN] Pb


  Does anyone no what 1% Pb in SnAg solder will do? I just got a solder
analysis done for my wave.



  Paul Stolar

  Materials Engineer

  Baker Atlas

  713-625-5376

  ---------------------------------------------------
  Technet Mail List provided as a free service by IPC using LISTSERV 1.8e
  To unsubscribe, send a message to [log in to unmask] with following text in
the BODY (NOT the subject field): SIGNOFF Technet
  To temporarily halt or (re-start) delivery of Technet send e-mail to
[log in to unmask]: SET Technet NOMAIL or (MAIL)
  To receive ONE mailing per day of all the posts: send e-mail to
[log in to unmask]: SET Technet Digest
  Search the archives of previous posts at: http://listserv.ipc.org/archives
  Please visit IPC web site http://www.ipc.org/html/forum.htm for additional
information, or contact Keach Sasamori at [log in to unmask] or 847-509-9700
ext.5315
  ---------------------------------------------------
  Technet Mail List provided as a free service by IPC using LISTSERV 1.8e
  To unsubscribe, send a message to [log in to unmask] with following text in
the BODY (NOT the subject field): SIGNOFF Technet
  To temporarily halt or (re-start) delivery of Technet send e-mail to
[log in to unmask]: SET Technet NOMAIL or (MAIL)
  To receive ONE mailing per day of all the posts: send e-mail to
[log in to unmask]: SET Technet Digest
  Search the archives of previous posts at: http://listserv.ipc.org/archives
  Please visit IPC web site http://www.ipc.org/html/forum.htm for additional
information, or contact Keach Sasamori at [log in to unmask] or 847-509-9700
ext.5315
  -----------------------------------------------------
  -----------------------------------------------------


---------------------------------------------------
Technet Mail List provided as a free service by IPC using LISTSERV 1.8e
To unsubscribe, send a message to [log in to unmask] with following text in
the BODY (NOT the subject field): SIGNOFF Technet
To temporarily halt or (re-start) delivery of Technet send e-mail to [log in to unmask]: SET Technet NOMAIL or (MAIL)
To receive ONE mailing per day of all the posts: send e-mail to [log in to unmask]: SET Technet Digest
Search the archives of previous posts at: http://listserv.ipc.org/archives
Please visit IPC web site http://www.ipc.org/html/forum.htm for additional
information, or contact Keach Sasamori at [log in to unmask] or 847-509-9700 ext.5315
-----------------------------------------------------