I agree with these guys suggesting that 600°F is a high temperature for rework if we mean 600°F measured on the board in in the molten solder. But I think we are talking set points of the hand tool. There are a lot of variables in the equation; thermal offset between the point of measurement and the actual tip, thermal mass of the tip relative to the work piece, heat transfer area . . . and as stated earlier, flux type.
 
All things being equal 750°F as a set point may be high for some types of equipment;  Pace hand tools for example where the operator can set the tip offset to compensate for known characteristics of the tips.
 
Hand soldering and touch-up is as much skill as science. A skillful operator can achieve good solder joint characteristics with the correct tip in a APE hand tool can get good results from set points as low as 500°F.
 
But 750°F may also be perfectly acceptable; Older Weller designs with magnetic switches for example. I have never even seen a 500°F tip for those Weller hand tools.
 
In a former life, I went down the path the initial poster is taking. I found the 600° setting on our hand tools caused a lot of trouble. We ultimately compromised at 700° as a maximum set point, and sometimes our operators complained and used 750°F (which is what they had preferred until I butted in).
 
Later, we added a new brand of hand tool to our production line and 600°F was the best general purpose temperature, and our operators rarely needed to use setpoints greater than 650°F.
 
The message here is Know Your Process, Know Your Equipment.
 
Golfers . . . How far does a three iron go? . . .    one with a hickory shaft?
 
 Guy Ramsey
American Competitiveness Institute
Senior Lab Technician / Instructor
610 362-1200 ext. 107