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July 1999

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Subject:
From:
Carol Handwerker <[log in to unmask]>
Reply To:
Leadfree Electronics Assembly E-Mail Forum.
Date:
Thu, 8 Jul 1999 12:16:35 -0400
Content-Type:
text/plain
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text/plain (154 lines)
NCMS tested seven lead-free solders and eutectic Pb-Sn - 

Solder - Liquidus Temperature
Sn-37Pb - 183°C
Sn-3.5Ag - 221°C
Sn-58Bi - 139°C
Sn-3Ag-2Bi - 220°C
Sn-2.6Ag-0.8Cu-0.5Sb - 211°C (CASTIN)
Sn-3.4Ag-4.8Bi - 210°C
Sn-2.8Ag-20In - 187°C
Sn-3.5Ag-0.5Cu-1Zn - 221°C

Among the reliability tests were thermal cycling of surface mount
reliability test vehicles (RTV-SM) tested for:

6673 cycles at 0°C/100°C
5000 cycles at -55°C/125°C

with 
84 J-leaded PLCC
132 gull-wing leaded BQFP
1206 discrete chip resistors - alumina body
1206 discrete chip capacitors - barium titanate body
44 castellated I/O LCCC (for getting early failure information for modeling
only)
on multilayer FR-4 epoxy boards.

The components on the RTV-SM represent a variety of commonly used surface
mount components. Component choice was based primarily on the expected
stress/strain response during thermal cycling as well as the lead shape,
body size, and availability in a daisy chain configuration. Components were
obtained either with a 100% Sn finish on the component leads, or with a
Sn/Pb finish that was stripped and refinished by a commercially available
Sn-dipping process. 

Components were connected daisy chained.  Performance was monitored
electrically and by cross-sections.  Double-sided assemblies were used for
electrical testing to maximize sample size, while single-sided assemblies
were used for cross sectioning to facilitate sample preparation.
Multilayer FR-4 epoxy glass boards were chosen for the RTV-SM to match
product requirements. Components were distributed across the board so that
each component type occupied both edge and central positions. Components
placed near the edge of the boards often fail earlier than those located
more centrally on the board. A commercially available immersion Sn finish
was used because it exhibited the best solderability in manufacturing trials.

Copies of the NCMS report with the test results and the CD-ROM with all
project information can be obtained at

http://www.ncms.org/3portfolio/1ProjectPortfolio/pubs.htm

 At 03:49 PM 7/7/99 EDT, you wrote:
>In a message dated 7/7/99 9:35:30, [log in to unmask] writes:
>>Hi, Werner,
>>What tests are sufficient to ensure "reasonable" reliability [of solder 
>joints]?
>>Carol
>
>Hi Carol ,
>This sure is a loaded question, and can not be answered by a brief statement 
>without being flip—so, you asked for it!
>Personally, and from experience, I rather assure solder joint reliability 
>using an adequate modeling approach, taking into account both the 
>physics-of-failure and the statistical failure distribution. The reason is 
>that it is no more error-prone than testing and much less expensive and 
>time-consuming. The time and cost factors of testing has led to test 
>short-cut, with sometimes catastrophic consequences.
>Using a 'Design for Reliability (DfR)'-approach, of course, requires a 
>reasonably good model. For near-eutectic Sn/Pb solders and their
derivatives, 
>we have the data on which a number of modeling approaches used in the 
>industry are based. But for many of the newer soldering alloys, including
all 
>of the lead-free solders, we do not have sufficient data to determine a 
>fatigue reliability model. Thus, until such time, any modeling requires 
>assuming that the solder in question behaves similar to Sn/Pb and
multiplying 
>some safety (actually ignorance) factor (>=2xlife to acceptable failure 
>probability).
>For the new solders, side-by side cyclic testing with eutectic (or 60/40) 
>Sn/Pb solder from -20<->+100C (125C if substrate glass transition
temperature 
>is at least 150C) with 15 minute dwells at each temperature extreme (24 
>cycles/day) with conventional chambers (or 5 minute dwells with chambers 
>modified to provide temperature uniformity in the whole test volume; ~100 
>cycles/day) with at least 32 equal continuity daisy-chains monitored with an 
>Anatech Event Detector for both solders, is necessary. This will give an 
>adequate data base to draw valid comparisons with near-eutectic Sn/Pb 
>solders, and, to me more importantly, from which a fatigue reliability model 
>can be derived. 
>Tests that are sufficient to ensure "reasonable" reliability will be totally 
>dependent on the product design together with its application. But to design 
>such a test, you have to have an appropriate fatigue reliability model from 
>which a valid acceleration factor for the test vis-a-vis the use conditions 
>can be determined. Electronic application vary from easily met reliability 
>reqirements for consumer products (~1,000 cycles (3 yrs) @ delta-T's ~10C & 
>10% acceltable failure probability) to difficult to meet requirements for 
>low-earth-orbit satellites (~90,000 cycles (10 yrs) @delta-T's ~35C &
0.001%) 
>or automotive-under-hood equipment (~10,000 cycles (~3 yrs) @ delta-T's
~100C 
>& 0.1%).
>
>Werner Engelmaier
>Engelmaier Associates, L.C.
>Electronic Packaging, Interconnection and Reliability Consulting
>7 Jasmine Run
>Ormond Beach, FL  32174  USA
>Phone: 904-437-8747, Fax: 904-437-8737
>E-mail: [log in to unmask], Website: www.engelmaier.com 
>
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>IPCWorks -October 25-28 featuring an International Summit on Lead-Free
Electronic
>Assemblies.
>Please visit IPC's Center for Lead-Free Electronics Assembly
>(http://www.ipc.org/html/leadfree.htm ) for additional information.
>For technical support contact Gayatri Sardeshpande [log in to unmask] or
847-790-5365.
>################################################################
>
>
**************************************
Carol A. Handwerker
Chief, Metallurgy Division
NIST 
100 Bureau Drive Stop 8550
Gaithersburg MD 20899-8550
Office:(301) 975-6158
Fax:(301) 975-4553
e-mail:[log in to unmask]

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To subscribe/unsubscribe, send a message to [log in to unmask]
with following text in the body:
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################################################################
IPCWorks -October 25-28 featuring an International Summit on Lead-Free Electronic
Assemblies.
Please visit IPC's Center for Lead-Free Electronics Assembly
(http://www.ipc.org/html/leadfree.htm ) for additional information.
For technical support contact Gayatri Sardeshpande [log in to unmask] or 847-790-5365.
################################################################

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