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July 1998

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Date:
Mon, 27 Jul 1998 16:44:21 -0600
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Ed,

When you say, "surface of the solder joint," do you mean a surface adjacent
to the original gold/tin location or had the IMC moved away to another
location?

Syed.

        -----Original Message-----
        From:   SEM Lab, Inc. [SMTP:[log in to unmask]]
        Sent:   Thursday, June 25, 1998 12:27 PM
        To:     [log in to unmask]
        Subject:        Re: [TN] Gold Coated Solder

        Bill,

        I have recently seen a number of instances where gold-tin
intermetallic compound (IMC) was on the
        surface of solder joints but not in the bulk solder.  I believe the
reason is that the density of
        the solid IMC is less than the molten tin-lead and there the IMC
floats to the surface prior to
        solidification.

        Ed Hare
        --

                       SEM Lab, Inc.
        Scanning Electron Microscopy and Failure Analysis
                       Snohomish, WA
                       (425)335-4400
                   http://www.sem-lab.com

        Bill Fabry wrote:

        > Deat "Techies":
        >
        > I have a "GOLDEN" opportunity for the experts to shine.  I have in
my possession
        > some SMT assemblies built on gold flash fabs that exhibit gold
residing on the
        > surface of the fillet, rather than being dissolved in the solder.
The fillet is
        > fully formed with no graininess or other visual anomilies.  The
phenomenon
        > occurs on ONE end of a MELF diode, not on both ends.  To answer
the obvious
        > question, it is NOT dependant on the diode polarity; it happens on
either end
        > but on one end only.
        >
        > I have digitally captured a couple of photos of the phenomenon.
If you need
        > pictorial representation, please e-mail me directly and I can
attach it to a
        > return e-mail.
        >
        > As you will see,  the gold remains on the surface of the fillet,
rather than
        > being dissolved in the fillet.   A slight scraping of the fillet
surface will
        > uncover the base solder with NO visual evidence of gold inside.
Other
        > terminations on other components do NOT exhibit this phenomenon.
The assembly
        > subcontractor is using standard NO-CLEAN solder paste (OMG
Americas 500ADV
        > NO-CLEAN 63SN). Unsoldered parts show a tin/lead termination,
indicating that
        > the gold has possibly migrated over the entire termination.
        >
        > My question:  What mechanism is at work to keep the gold from
totally dissolving
        > into the Sn/Pb paste after it leaves the fab during reflow?
        >
        > Thanks for the help.
        >
        > Bill Fabry, Sr. Manufacturing Engineer
        > Plantronics, Inc.
        > 345 Encinal Street
        > Santa Cruz, Ca. 95060
        > (408) 458-7555
        >
        > [log in to unmask]
        >
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