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Reply To: | TechNet E-Mail Forum. |
Date: | Fri, 23 Jan 1998 09:13:59 -0600 |
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Good morning, Karen; you said:
>1. Electromigration requires DC voltages and currents.
>
> a. AC voltages and and current will not cause
> the electrodissolution of copper, silver,
> tin or lead. The only materials that corrode
> with imposed AC (<~10 kHz). are amphoteric
> materials, like aluminum.
>
> b. AC voltage and currents will not allow the
> the electrodeposition of any metal that I know.
> The metal deposited during one half wave will
> dissolved during the 2nd half wave.
>
>2. Imposing a small AC voltage (5 to 50 mV) on top
> of a DC voltage and looking at the resulting
> small AC current is good way of studying
> electrochemical reactions like dissolution and
> deposition of metals. The frequencies used range
> from 1 mHz to 100 kHz. Frequencies over 100 kHz,
> such as RF, are not useful for looking at
> electrochemical reactions because the chemical
> kinetics of these reactions are too slow.
1) I _love_ that kind of talk.
2) Been waiting a long time for someone to techno-incinerate Graham Naisbitt.
thanks,
Jerry
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