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November 2013

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From:
"David D. Hillman" <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, [log in to unmask]
Date:
Wed, 27 Nov 2013 13:53:27 -0600
Content-Type:
text/plain
Parts/Attachments:
text/plain (218 lines)
Hi Gregg - I use the term Brittle Nickel failure a bit sloppy but George 
and I are focused on what is happening at the solder/IMC/pad interface. As 
George pointed out, soldering to copper (i.e. immersion silver or 
immersion tin or HASL)  creates a stronger solder joint than soldering to 
nickel (i.e. ENIG) because of the IMC structure that is formed. Werner had 
a couple of good published articles detailing/contrasting some of the 
inherent differences of the two combinations. I always view Brittle Nickel 
failure as a soldering issue and not a plating/fabrication issue since the 
formation of that interface and the condition of the IMC is the critical 
aspect of how the solder joint was formed.  Brittle Nickel failure would 
have the solder joint cracking at the IMC/pad interface - looking at 
Andy's pictures, I assumed that was where the crack was but George has a 
point in that a higher magnification photo is really needed for a more 
accurate assessment. You can failure a perfectly good ENIG solder joint 
with excessive stress due to the brittle nature of that interface. The 
good thing for the users of ENIG is that the majority of the time the ENIG 
solder joint is capable of withstanding the product use environment 
stresses. Hope that helps.

Dave



From:   Gregg Owens <[log in to unmask]>
To:     <[log in to unmask]>
Date:   11/27/2013 12:04 PM
Subject:        Re: [TN] Separation between the BGA solder ball and pad on 
the PCB
Sent by:        TechNet <[log in to unmask]>



For the slow of mind, what causes brittle nickel - PCB fabrication or 
soldering process or both?

Gregg

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of David D. Hillman
Sent: Wednesday, November 27, 2013 9:56 AM
To: [log in to unmask]
Subject: Re: [TN] Separation between the BGA sodler ball and pad on the 
PCB

Hi Steve - thanks for posting up the pictures. Looks like a brittle nickel 
fracture failure mode to me - the failure is at the IMC/copper pad 
interface and the dye & pry shows progressive crack growth.

Dave Hillman
Rockwell Collins
[log in to unmask]



From:   Steve Gregory <[log in to unmask]>
To:     <[log in to unmask]>
Date:   11/27/2013 11:49 AM
Subject:        Re: [TN] Separation between the BGA sodler ball and pad on 

the PCB
Sent by:        TechNet <[log in to unmask]>



Hi Andy,

Got all of your pictures and attachments. All the cross-section pictures 
are here:

http://stevezeva.homestead.com/A1.jpg
http://stevezeva.homestead.com/A16_1.jpg
http://stevezeva.homestead.com/A16_2.jpg
http://stevezeva.homestead.com/T16_1.jpg
http://stevezeva.homestead.com/T16_2.jpg

Your dye & pry is here:

http://stevezeva.homestead.com/256BGA-mod_for_TechNet.pdf

Lastly, here is the reflow profile:

http://stevezeva.homestead.com/Andy_s_Reflow_Profile.jpg


Steve 

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of andi1978
Sent: Wednesday, November 27, 2013 6:56 AM
To: [log in to unmask]
Subject: Re: [TN] Separation between the BGA sodler ball and pad on the 
PCB

George,
 First apologize for not timely replying to this topic, I am living within 
Europe time zone.
Here more facts about this condition and as well to clarify some questions 
already posted.
I did re-sent pictures again and in addition will send 2 pages of our dye 
&amp; pry report document we did in March this year (from the same 
subcontractor).
As George W. already indicated we can eliminate lab issue and poor sample 
preparation doing the dye &amp; pry test. Fortunately I am in possession 
of such a report from March 2013 before our BGA cross-section from 
September 2013. The short message is that there are evidences of dye 
ingression at the PCB pad level and only existing in the corners of the 
BGA package. To clarify George's question on completed inter-metallic 
fusion. What I can see from pictures I sent to Steve, the solder paste 
perfectly melted with the BGA solder balls and the sample board was fully 
cooled. The cross-section was done after the initial reflow (single 
thermal processing). 
The whole board is double sided assembly but because of the need for 
cross-section, only the BGA component was populated (no other parts were 
assembled).
There was a request to send the reflow profile to Steve, have done that 
now. That's all I know and far I can go myself.
I kind of excluded PCB warpage due to small size of the sample board
(65mm/70mm/1.5mm) and that this PCB was held in the thermal panel secured 
with 4 clamps during reflow (single pass).
Regards,
Andy
27 November 2013 3:02 "Wenger, George M. [Contractor]" 
&lt;[log in to unmask]&gt; wrote:
Andy,
Once Steve has your photomicrographs of the cross section posted it will 
be much easier to provide meaningful advice. Without a photograph and 
additional information one can only guess. You indicated separation 
occurred after the reflow process was completed because there is evidence 
of completed inter-metallic fusion. I assume when you say "after the 
reflow process you most likely mean after the solder melted and then 
cooled below liquidus. Is this a single sided reflow assembly or a double 
sided reflow assembly? Where the separations discovered after the first 
reflow or the second reflow? 
Regards,
George
George M. Wenger
Failure Signature &amp; Characterization Lab LLC
609 Cokesbury Road, High Bridge, NJ 08829
(908) 638-8771 Home (732) 309-8964 Mobile
E-mail: [log in to unmask]
[log in to unmask]
-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Andrzej Zielinski
Sent: Tuesday, November 26, 2013 10:33 AM
To: [log in to unmask]
Subject: [TN] Separation between the BGA sodler ball and pad on the PCB 
Dear Colleagues ..
I am facing an issue with the BGA part where in three locations we found 
separation between the BGA solder balls and pads on the PCB (ENIG finish).
This condition was discovered during the cross-section that we have 
requested from our local lab.
I can share few pictures I have taken from our report (can't attach the 
whole document as this report is confidential to our business).
Basically this BGA is the plastic ACTEL package 896 pins, SAC305 finish, 
soldered with leaded process using 62Sn/36Pb/2Ag solder paste. Temperature 
was slightly elevated to accommodate SAC305 solder finish from the BGA 
package.
The separation condition we have observed was only found in location A1,
A16 &amp; T16 which are the corners of the BGA package. As well all 3 
separations occurred after the reflow process was completed because there 
is an evidence of completed inter-metallic fusion. 
In location A16 &amp; T16 you can see the copper is protruding of the pad 
but I have been told this is not an issue and cause of the separation.
I was considering package or PCB warpage as the cause of this separation 
or something related to cooling the board after reflow.
I asked our lab to measure the height of the solder balls across row A 
&amp; T and they all deem to be ok.
I have asked to check for the phosphorus content as the pad level to see 
if this is related to black-pad symptom and the phosphorus was measured as 
10.3%.
So far the board assembly house is adamant their reflow profile is 
correct.
PCB manufacturer is confident with their PCB and pointing to the assembly 
house.
There is a thought about poor sample preparation where the separation 
issue would be caused by the lab (during cross-section).
We are attempting to perform another cross-section on different board but 
here I am not really sure if this is the right way to go (extra cost).
Because I have never seen such a defect, I am not sure what should be the 
next step to take.
Any advice guys ?
Andy
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