Julie,
Are you saying you are attempting to remove the gold coating from QFN ground
pads before using them in production?!
Bev
Blackberry

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Julie Silk
Sent: Wednesday, May 29, 2013 7:16 PM
To: [log in to unmask]
Subject: Re: [TN] Gold Removal

A few other points:
We have found that the gold-tin intermetallics that form when the gold
plating dissolves into the bulk solder will migrate to the nickel plating.
They seek out the nickel, which lowers the energy of the compound when it
dissolves into the gold-tin, and since nickel doesn't move very fast into
the bulk, the gold-tin moves to the interface and you'll have (Au, Ni)Sn4.
This gold-tin layer itself is what's brittle, not so much the gaps left
behind from when it moved.  At least that's what we saw.  We also saw that
when there is copper on one side of the joint (no Ni plating), the AuSn4
didn't move into a continuous brittle layer.  The AuSn4 became (Au, Cu,
Ni)Sn4 --  the theory is that the Cu is taken in where Ni would have gone.
Cu migrates faster, so is more available in the bulk.  So, you can get away
with higher Au content when you don't have nickel plating on both sides of
the joint.  But not too much more Au.  You should still be worried above 5
wt%

What I want to know is if anyone has successfully removed gold from a QFN
without the ground pad being too lumpy to solder or the part being fried
from excessive heat.


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