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Subject:
From:
Joyce Koo <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Joyce Koo <[log in to unmask]>
Date:
Mon, 8 Apr 2013 15:17:37 +0000
Content-Type:
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text/plain (226 lines)
Double layer conduction?  Might be shielding layer for EMI/EMC.  That would be perfect application for PE. 

Joyce Koo
Researcher
Materials Interconnect Lab
Office: (519) 888-7465 79945
BlackBerry: (226) 220-4760


-----Original Message-----
From: Mike Fenner [mailto:[log in to unmask]] 
Sent: Monday, April 08, 2013 10:09 AM
To: 'TechNet E-Mail Forum'; Joyce Koo
Subject: RE: [TN] copper nanosolder--fyi

Good summary Joyce. 
I think its clear that PE, with or without nano will not be replacing high
speed digital circuitry for some time yet, its opportunities are elsewhere.
There are plenty of examples already. Having said that it's interesting to
look at display technology and the additional printed circuitry applied to
conventional metal track PCBs. That's kind of PE by the back door. To me PE
is just a subset of 3D printing, added layer manufacturing, call it what you
will, in fact is part of it. 

Regards 
 
Mike Fenner 
Bonding Services & Products
M: +44 [0] 7810 526 317 
T: +44 [0] 1865 522 663
-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Joyce Koo
Sent: Monday, April 08, 2013 2:47 PM
To: [log in to unmask]
Subject: Re: [TN] copper nanosolder--fyi

Many thanks Harvey.  I would very much interest to know the detail of the
presentation.  The nano particles are utilized in printed electronics, in
various elements and organic conductive media to improve conductivity and
flexibility.  Normally, printed electronics are processed in low temperature
with large surface contact area (roll to roll printing).  Therefore, it can
be flexible and thin, the resistance short coming of the nano-particles due
its large surface/interface characteristics (sometimes, it is hopping rather
than normal conduction mechanism) are compensated by large conduction
contact surfaces and thin joints.  

Sintering/fusing of the nano-particle can be done at lower temperature due
to highly active surface energy, however, unless performed under pressure,
you might get un-controlled re-crystallization and growth of the grain,
resulted preferential growth of certain orientation of grain and leave some
voids behind (low angle co-incidence grain boundary, as well as twining, are
stable boundary, but not high angle gain boundary)- you might get more
conductivity loss in high frequency and resistance increase. Of course, all
the oxidation must be taking care of (copper is very readily oxidized, even
with OSP coated, with that much surface area (nano particle).  Acid media is
more less like a flux can take care some of surface oxidation, but you still
need to control the coalescence and growth (not all orientation are grow at
same rate...).  

The existing solder interconnect is heading towards smaller, more compact
(solid) joints, for example, flip chip, or TSV for high speed, high density
interconnect (in line with the high density IC with node of <20 nm).  The
solder interconnect joints more in the 3D stack, rather than 2D in printed
electronics.  High surface/interface might be good for some application,
such as low frequency, low temperature application, I am a bit curious how
it can be apply to the high frequency, high I/O, short and dense
interconnect at lower voltage, and high device temperature (current
processor dissipated 40-100W in some cases).  Looking forward to see the
presentation (I would really appreciated if you can share with us).  I
haven't been in the field for long time, Looking forward to update my
knowledge.  Thanks.  My 2 cents. 
Best regards,




Joyce Koo
Researcher
Materials Interconnect Lab
Office: (519) 888-7465 79945
BlackBerry: (226) 220-4760


-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of harvey
Sent: Saturday, April 06, 2013 9:16 PM
To: [log in to unmask]
Subject: [TN] copper nanosolder--fyi

Biltmore Santa Clara for dinner (or non-dinner) 
            June 12, 2013.

Dr. Zinn's bio and abstract are at the end. 
            Lockheed's nano-copper solder is an answer to the lead-free
solder 
            fiasco.
Remember "the non-solution to the non-problem",
that 
            is, until we get rid of most solder altogether, most solder
paste, 
            anyhow.


            
              
              
                Speaker:
                Alfred Zinn, Lockheed Martin Space 
                  System Company ATC, Senior Scientist
              
                Abstract:
                
                  NanoCopper Materials Platform for Electronic 
                  Packaging and Printed Electronics with 200 °C Processing 
                  Temperature

                  The Advanced Technology Center of the Lockheed Martin 
                  Corporation has developed a nanocopper-based material that
can 
                  be fused to bulk copper around 200 °C taking advantage of
the 
                  rapidly decreasing fusion temperature with decreasing
particle 
                  size at the nanoscale. The nanocopper material has the 
                  potential to replace tin-based solder to eliminate whisker

                  growth and mechanical reliability concerns encountered
with 
                  current lead-free solder. Fully optimized, the fused
copper is 
                  expected to exhibit 10-15x electrical and thermal
conductivity 
                  improvements over tin-based materials currently in use.
The 
                  materials platform is enabled by our scalable Cu
nanoparticle 
                  fabrication process employing a low cost solution-phase 
                  chemical reduction approach. A proprietary mixture of 
                  surfactants controls particle size and size distribution
as 
                  well as stabilizing the particles preventing particle
growth 
                  and oxidation, which would otherwise degrade its activity.
We 
                  have demonstrated assembly of fully functional LED test
boards 
                  using a paste formulated with nanocopper that exhibits a 
                  consistency very similar to standard tin-based solder
paste. 
                  To date, we have demonstrated 26-pin through-hole
connector 
                  assembly and a variety of surface mount components. We 
                  demonstrated feasibility of drop-in solder replacement
using 
                  standard stencil and pick & place packaging equipment as 
                  well as demonstrated feasibility of using the material for

                  printed electronics applications.
              
                 
                Dr. Zinn 
                  received his Doctor of Science degree in Chemistry in 1990

                  from the Philipps University, Marburg, Germany. Following 
                  completion of his graduate studies, Dr. Zinn spent five
years 
                  at UCLA as a lecturer and conducting postdoctoral research
on 
                  low-temperature CVD for interconnect, diffusion, and
migration 
                  barrier deposition, as well as magnetic nanomaterials
design 
                  and synthesis. In 2004, he joined Lockheed Martin Space 
                  Systems Company Advanced technology Center in Palo Alto,
CA 
                  developing high-temperature materials systems,
nanostructured 
                  functional materials (electrical, thermal,
thermoelectric), 
                  modeling quantum/superlattice structures and devices, high

                  performance energy conversion devices (solar, high & low 
                  quality heat conversion). He holds seven patents in
materials, 
                  structures and processing, two THz technology patents,
with 
                  ten additional patents pending (multiple international 
                  filings) as well as four trade secrets. He has authored or

                  co-authored over 20 archival journal publications,
including 
                  book chapters in "The Chemistry of Metal CVD" as well as
the 
                  "Encyclopedia of Inorganic 
            Chemistry.

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