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February 2011

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Subject:
From:
"David D. Hillman" <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, [log in to unmask]
Date:
Fri, 11 Feb 2011 07:06:29 -0600
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Hi George! Very nice examples and great info! I'll be putting those 
pictures in my photo gallery collection as tarnish examples. Someone at 
one of the IPC meetings made the statement that "Immersion silver surface 
finishes try to provide a visual appearance of how their solderability 
might be changing over time" - I thought that statement emphasized one of 
immersion silver's positive attributes in comparison to other pwb surface 
finishes we use as an industry.

Dave



"Wenger, George M." <[log in to unmask]> 
Sent by: TechNet <[log in to unmask]>
02/10/2011 09:40 PM
Please respond to
TechNet E-Mail Forum <[log in to unmask]>; Please respond to
"Wenger, George M." <[log in to unmask]>


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Subject
Re: [TN] IPC-4553






Kevin,

I read your Tuesday, Feb 8th posting and was going to respond but I got 
tied up with critical issues that I couldn't put off.  Now that things 
have settled down I figured it would still be good to respond especially 
after reading the answers Dave and Richard provided which I agree with.

Dave,

I totally agree with your Immersion Silver Visual Appearance Rule of 
Thumb.  When I read Kevin's TN post I decided to go through my desk and 
find some really old immersion silver plated boards I know I had saved. In 
the attached PDF file (I've copied Steve in hopes he can post the file on 
his site) are photographs of National Center for Manufacturing Science 
(NCMS) test boards that were plated with immersion silver boards during 
Week 04 of 1997.  Jim Reed sent me these two boards and I've had these two 
test boards in my desk in a non-sealed plastic bag for 15 years.  When I 
opened the bag it was obvious that the board that the immersion silver 
plated pads on the top board had a yellowish-brown tint compared to the 
board that was at the bottom.  I haven't done any SEM/EDX analysis on 
these two boards but we have done lots of analysis on other immersion 
silver boards with this type of discoloration and know this is mild 
tarnish.

There are also photographs of the electromigration boards that were plated 
with immersion silver during Week 22 of 2003 as part of the joint work 
between UL and IPC 3-11g committee.  I had a few of these board wrapped in 
aluminum foil in my desk for the past 7 1/2 years.  As you know, immersion 
silver has been our surface finish of choice since 1997 even before UL 
changed their silver testing requirements.  I had opened the 'A' board 
several times to show visitors to our Lab and as a result the bottom edge 
of the aluminum foil was torn leaving the bottom edge of the board exposed 
to our Lab environment.  You can see some discoloration on the pads at the 
bottom edge of the board.  Nevertheless I am sure they are solderable.

In the many years we've been using immersion silver we have not 
experienced any reliability issue associated with the immersion silver 
surface finish.  Our products aren't deployed in space but they are 
deployed worldwide in outdoor environments even in countries with known 
air pollution issues.  We do get failed products returned for repair or 
replacement but there hasn't been a case where a product has failed due to 
the immersion silver surface finish used on PCBAs.

We don't have a visual appearance guideline but I'm often asked for 
questions about discolored or stained boards.  The following are some of 
those questions; "We found some 2 or 3 year old boards in our warehouse 
and we'd like to use them for production but they are discolored.  Can we 
use them for production?"  or "A leak developed in the roof of our 
storeroom and a group of boards got wet and after we dried them they look 
a little discolored and there is some staining.  Can we use them for 
production?."  Being and FMA / Reliability engineer my usual answer is to 
take a small sample of the boards and do your normal solder assembly (you 
know me "Nothing test soldering better than soldering") and see how they 
solder and then do an extended burn in to make sure they are okay. 
Unfortuantley, the typical response I get is "The boards were expensive 
and I need to use them to meet production orders."  Fortunately, there has 
never been solder assembly issues or reliability issues with these stained 
board.  Our telecommunication customers are extremely concerned about 
product reliability because they deploy out product on towers in vastly 
different environmental conditions and the last thing they want are 
failures where someone has to go out and climb a tower and replace 
products.  Because of their reliability concern we keep very good records 
of product serial numbers and issues experienced in manufacturing so if 
the use of stained boards were causing a reliability issue we could would 
know.  As I said previously we've never experienced any reliability issue 
associated with the use of immersion silver surface finish.

I've copied Steve on this email in hopes that he can post the attachment 
on his web site so other TNers can see the 15 and 7 1/2 year old immersion 
silver boards.


Subject: Re: IPC-4553 
From: David D. Hillman 
Reply-To: TechNet E-Mail Forum <[log in to unmask]>, 
[log in to unmask] 
Date: Wed, 9 Feb 2011 10:17:31 -0600 
Content-Type: text/plain 

Hi Richard - very good discussion! I have the luxury of having a SERA 
tester to measure the oxidation state of my immersion silver pwbs so I can 

determine just have bad things are getting. Here is some wording we use on 

our product floor to assist with the "changing visual appearance" of 
immersion silver finishes. This rule of thumb isn't perfect but has been 
helpful.

Immersion Silver Visual Appearance Rule of Thumb:
Immersion silver surface finishes will discolor as a printed wiring board 
goes thru the assembly process. This discoloration is oxidation and not 
corrosion with one exception. The typical discoloration has a yellow to 
goldish tan to light brown visual appearance which is cosmetic in nature. 
If the pwas have a dark brown to black visual appearance then they have 
been either mishandled, were left damp going into their ESD bags or the 
plating is bad. So rules of the road:

1) If the pwas have a yellow to goldish tan visual appearance in an area 
that is not going to be soldered, no action required.

2) If the pwas have a yellow to goldish tan visual appearance in an area 
that is going to be soldered, no action required unless we encounter 
soldering issues. 

3) If the pwas have a light brown visual appearance in any areas of the 
pwa, then we should review our handling procedures to make sure we are not 

putting pwas in bags damp or not handling the pwas by the edges. We should 

also inspect the bare pwbs in stock to see if they have a light brown 
appearance prior to assembly.

4) If the pwas have a dark brown to black visual appearance in any areas 
of the pwa, then we have a problem and need to find root cause.

As you detailed, rubber bands and tape cause major issues for immersion 
silver pwbs turning black due to sulfur and chloride contamination

Dave Hillman
Rockwell Collins 
[log in to unmask]



"Stadem, Richard D." <[log in to unmask]> 
Sent by: TechNet <[log in to unmask]>
02/09/2011 08:49 AM
Please respond to
TechNet E-Mail Forum <[log in to unmask]>; Please respond to
"Stadem, Richard D." <[log in to unmask]>


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Subject
Re: [TN] IPC-4553






In terms of losing solderability on the secondary side after a single trip 

through the reflow, I think you have immersion silver finish confused with 

immersion tin. Immersion silver does not usually degrade significantly 
after a single reflow excursion.
But again, it depends (ka-ching).
There are many immersion silver plating products, some not as good as 
others, and there is a huge variation amongst the plating companies that 
apply these products. Like any other plating, it depends on which product 
you use, and which plating company or PWB fabricator you use. Some IAg 
products have a much superior co-inhibitor that prevents tarnishing and 
oxidation.
Minor tarnishing (yellowing) of immersion silver has very little effect on 

the DPMO of a given PWB. Black areas caused by direct contact with 
sulfur-bearing desiccant packages, rubber bands, tape, paper (including 
the Moisture Indicator cards) are a completely different story; these will 

have significant impact on solderability, and the flux has little or no 
effect on this.


-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Glidden, Kevin
Sent: Wednesday, February 09, 2011 8:33 AM
To: [log in to unmask]
Subject: Re: [TN] IPC-4553

Good point.  Solderability depends heavily on your flux I would say. Those 

using a high activity, halide containing formulation would have an easier 
time than those with ROL0.  Plus, the additional predicament is that the 
oxidation may be minor when the PCBs are received, and they solder just 
fine, but after 6 months or so in stock it is worse, or even after 1 trip 
down the reflow oven making Side 2 unsolderable.


-----Original Message-----
From: Jack Olson [mailto:[log in to unmask]] 
Sent: Wednesday, February 09, 2011 9:11 AM
To: [log in to unmask]; Glidden, Kevin
Cc: Jack Olson
Subject: Re: IPC-4553

Good question.... and when looking at an actual board, how is one to 
determine 
visually if we are looking at "staining" or "oxidation/corrosion"? 
Inquiring minds 
want to know. 
(many would say that even oxidized boards are solderable and acceptable. 
right? I think I just read that somewhere...)

Jack

.
On Tue, 8 Feb 2011 09:20:44 -0500, Glidden, Kevin 
<[log in to unmask]> wrote:

>Morning everyone,
>I have a question on IPC-4553, specifically, section 3.1 "Visual", and 
specifically regarding staining of immersion silver.  The text states "The 


coverage shall be complete and the finish shall be uniform on the surface 
to be 
plated (see Figures 3-1 through 3-5 for properties visually identified 
with IAg 
plated surfaces)"  Figure 3-1 shows 'Example of Uniform Plating", with no 
staining.  Figures 3-2 through 3-5 show staining.  Is this to imply 
(without text 
to support) that any staining of immersion silver is determined to be non-
uniform and therefore a defect?
>Thanks.



Regards,
George
George M. Wenger
Senior Principal Reliability / FMA Engineer
Andrew Corporation - Wireless Network Solutions
40 Technology Drive, Warren, NJ 07059
(908) 546-4531 Office (732) 309-8964 Mobile
E-mail: [log in to unmask]

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Glidden, Kevin
Sent: Tuesday, February 08, 2011 9:21 AM
To: [log in to unmask]
Subject: [TN] IPC-4553

Morning everyone,
I have a question on IPC-4553, specifically, section 3.1 "Visual", and 
specifically regarding staining of immersion silver.  The text states "The 
coverage shall be complete and the finish shall be uniform on the surface 
to be plated (see Figures 3-1 through 3-5 for properties visually 
identified with IAg plated surfaces)"  Figure 3-1 shows 'Example of 
Uniform Plating", with no staining.  Figures 3-2 through 3-5 show 
staining.  Is this to imply (without text to support) that any staining of 
immersion silver is determined to be non-uniform and therefore a defect?
Thanks.

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