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From:
Gregg Owens <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Gregg Owens <[log in to unmask]>
Date:
Fri, 28 Jan 2011 07:27:55 -0800
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In addition to a good night's rest at the Holiday Inn, I think Dave had his Wheaties this morning! Yes, excellent post.

Gregg Owens | Technical Writer
Wavestream Corporation
 (909) 451-6089 | [log in to unmask]

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Stadem, Richard D.
Sent: Friday, January 28, 2011 7:26 AM
To: [log in to unmask]
Subject: Re: [TN] Tantalum Capacitors and double sided reflow

Good post, very informative. Thanks Dave!

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of David D. Hillman
Sent: Friday, January 28, 2011 9:08 AM
To: [log in to unmask]
Subject: Re: [TN] Tantalum Capacitors and double sided reflow

Hi Phil - the issue/concern with Ta capacitors comes from the metallurgy 
and internal construction of the component. Typical capacitors are 
constructed utilizing two electrodes separated by a dielectric. The 
electrodes can be separated into an anode and cathode. The medium used as 
a dielectric can be many types of material, potentially ranging from air 
to metal. The Ta capacitors are designed with a Ta anode, a solid MnO2 
cathode, and a Tantalum Pentoxide (Ta2O5) dielectric. The advantage of Ta 
capacitors is their high volumetric efficiency, basic reliability, and 
process compatibility compared to other capacitors of similar size. Their 
highly stable capacitance and frequency characteristics and typically very 
low Equivalent Series Resistance (ESR) make them attractive when used for 
filtering in power supply designs. A final advantage of Ta capacitors is 
the self-healing property they possess. For any random defect site within 
the dielectric (Ta2O5), the current through this defect area causes 
localized over-heating.  The result of this localized heating depends in 
large part on how rapidly it occurs.   If the temperature rise due to the 
defect current flow is relatively gradual (over a few tens of 
microseconds, which is typical for a current limiting situation), then the 
MnO2 becomes resistive and the Tantalum is said to have healed itself. If, 
on the other hand, the heating is rapid (over a few microseconds, which is 
typical of an unlimited power on situation with no series resistance) the 
defect site itself may become very hot before the neighboring MnO2 becomes 
resistive. This results in a self feeding ignition failure as the hot spot 
pulls in additional Oxygen from the MnO2 layer - your basic "metal fire". 
For a more complete details on this failure phenomena, Kemet has an 
excellent detailed summary of this in their publication: Kemet Electronics 
Corporation Tantalum Applications Notes, Surge Step Stress Testing in 
Tantalum Capacitors (note - I am not an EE but I did stay at a Holiday Inn 
last night...........).

Ok, so why does all of that matter? The thermal excursions of industry 
standard soldering processes - reflow, vapor phase, manual - can 
cause/create dielectric defects. The Ta capacitor component suppliers 
screen/test the Ta capacitors to make sure there is as much thermal 
excursion robustness in the components as possible but statistics isn't 
their friend when there are millions of devices produced. We conducted 
testing here at Rockwell Collins to measure and quantify the "typical" 
impact our various soldering processes had on the Ta capacitors. We have 
put into place specific rules for Ta capacitors based on those testing 
results. My guess is that the comment you have heard "....can't be 
reflowed twice..." is based on someone taking a conservative approach on 
the issue. I do know that many product designers de-rate Ta capacitors to 
achieve the same effect.

Dave Hillman
Rockwell Collins
[log in to unmask]





Phil Bavaro <[log in to unmask]> 
Sent by: TechNet <[log in to unmask]>
01/27/2011 03:25 PM
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TechNet E-Mail Forum <[log in to unmask]>; Please respond to
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Subject
[TN] Tantalum Capacitors and double sided reflow






I recently heard from a customer who is concerned about our designs
having tantalum caps on the second side of double sided Sn63Pb37 circuit
card assemblies.

 

This is news to me but maybe something has happened in the world that I
missed.....wouldn't be the first time.

 

In a nutshell, I am hearing that tantalums cannot be reflowed
twice....yet I read in Kemet literature that the reliability specs are
based on three time reflows for resistance to soldering heat.

 

And I have reflowed tantalums at lead free temperatures as well without
seeing failures.

 

Any help would be appreciated.

 

Phil

 

 


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