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Subject:
From:
Dennis Fritz <[log in to unmask]>
Reply To:
(Leadfree Electronics Assembly Forum)
Date:
Tue, 9 Mar 2010 20:53:17 -0500
Content-Type:
text/plain
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text/plain (240 lines)
All - I have no problem with Joe's data. but here is what the EU (at the recommendation of the Germans and Slovakians) is using.  Read away -  the good parts about males is toward the end. ECHA is the European Chemicals Agency.  


http://echa.europa.eu/doc/consultations/svhc/svhc_axvrep_germany_cmr_boric_acid.pdf




-----Original Message-----
From: [log in to unmask]
To: [log in to unmask]
Sent: Tue, Mar 9, 2010 8:26 pm
Subject: Re: [LF] More importantly.... 8 new substances proposed for REACH control


Thanks Denny, 

ound this which supports your comments but look at the levels  required... 

oxicologic studies on borax and boric  acid  



eferences and further  reading may be available for this article. To view 
eferences and further  reading you must purchase this  article.


Robert J. Weir, Jr.   
azleton  Laboratories, Inc., Falls Church, Virginia, 22046, USA 
 
ussell S. Fisher Office of the Chief Medical Examiner  of the State of 
aryland, Baltimore, Maryland 21201, USA
eceived 22 July 1971.  
vailable online 27 September  2004. 

n Sprague-Dawley rats the acute po LD50 values for borax were 4.5 g/kg and 
4.98 g/kg in males and females. respectively; boric acid, 3.45 g/kg in 
ales and  4.08 g/kg in females. In Long-Evans male rats the LD50 values for 
orax and  boric acid were 6.08 g/kg and 3.16 g/kg, respectively. In 90 day 
eeding  studies, rats tolerated both borax and boric acid at 525 ppm boron 
quivalent.  Dogs displayed no adverse effect at 175 ppm of borax (as boron 
quivalent) and  525 ppm of boric acid (as boron equivalent). In rats, high 
oron levels at 1750  and 5250 ppm of both compounds caused growth 
uppression, decreased food  utilization efficiency, degeneration of gonads and 
kin 
esquamation on the paws  and tails. At the 1750 ppm level, both boron 
ompounds produced testicular  atrophy in all male dogs. Two year dietary 
eeding 
tudies indicated that both  borax and boric acid could be tolerated by rats 
nd dogs at 350 ppm boron  equivalent. Rats fed dietary boron compounds at 
170 ppm levels showed toxic  signs which were found to be similar to those 
bserved in subchronic studies.  Testicular degeneration was also observed in 
ats and dogs fed 1170 ppm levels.  Reproduction studies revealed that rats 
ed both borax and boric acid at 1170  ppm boron equivalent were sterile. 
oth compounds at 350 ppm boron equivalent  had no adverse effect on 
ertility, lactation, litter size, weight and  appearance.

o it goes...

oe




n a message dated 3/9/2010 5:14:09 P.M. Pacific Standard Time,  
[log in to unmask] writes:
Yes, I know about all the "good" health applications of boric acid.  
owever, in low doses, I it does not kill you, but damages the reproductive  
ystem - seems I read particularly males.  Soooooo, that makes it a  mutagen - 
nd hence, "toxic".   Remember my rant a month ago that  started with "toxic 
omputers".  Never mind that its lethal oral does is  comparable to table 
alt - as you point in your post.  Just remember the  three catagories of 
toxic" now - 


PBT  – Persistent,  Bioaccumulative,  and Toxic  
CMR  – Carcinogenic,  Mutagenic,  or toxic for Reproduction  
vPvB  – very  Persistent  and very  Bioaccumulative  







-----Original  Message-----
rom: [log in to unmask]
o: [log in to unmask]
ent: Tue,  Mar 9, 2010 7:02 pm
ubject: Re: [LF] More importantly.... 8 new substances  proposed for REACH 
ontrol

http://_www.stuffinanutshell.com/health/boricacid.html__ 
http://www.stuffinanutshell.com/health/boricacid.html_)   
_http://www.stuffinanutshell.com/health/boricacid.html_ 
http://www.stuffinanutshell.com/health/boricacid.html) ) 
 
 
 
 
 
In a message dated 3/9/2010 3:58:38 P.M. Pacific Standard Time,  
[log in to unmask] (mailto:[log in to unmask])  writes:

Thanks  Nigel.  

Here in the US, the Aerospace Industries Association  EH&S committee sent 
this around yesterday asking where these might be  used.  I am no expert 
n 
fiberglass, but boric acid is listed as an  ingredient in E-Glass, that is 
borosilicate glass.  I am not sure REACh  listing would cripple the supply 
f 
boric acid as an intermeidate, but the  loss of E-glass in laminate would 
probably be worse than the lead-free  issue.  Anyone on here a fiberglass 
expert?  

I think  fluoroborate plating is way down in board fab, but may not be 
gone.   

Any further impacts to report from the world of circuit  boards?

Denny Fritz
SAIC, Inc




-----Original  Message-----
From: Nigel Burtt <[log in to unmask] (mailto:[log in to unmask]) >
To:  [log in to unmask] (mailto:[log in to unmask]) 
Sent: Tue, Mar 9, 2010 4:16 pm
Subject: [LF] More  importantly.... 8 new substances proposed for REACH 
control


The  eight substances suggested for consultation are:   
Trichloroethylene
Boric acid
Disodium tetraborate,  anhydrous
Tetraboron disodium heptaoxide, hydrate
Sodium  chromate
Potassium chromate
Ammonium dichromate
Potassium dichromate  
See:  
_http://echa.europa.eu/doc/press/pr_10_03_svhc_consultation_20100308.pdf_ 
http://echa.europa.eu/doc/press/pr_10_03_svhc_consultation_20100308.pdf) 


igel  Burtt
NJAYBEE ASSOCIATES 
EL: 44-8454-710989
OBILE:  44-7941-232900
KYPE: nigelburtt
ww.nigelburtt.co.uk |  [log in to unmask] 
mailto:[log in to unmask]) 


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