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October 2009

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Subject:
From:
"David D. Hillman" <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, [log in to unmask]
Date:
Fri, 23 Oct 2009 09:24:27 -0500
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text/plain (1588 lines)
Hi Werner - there is a very good Dye & Pry testing procedure in the 
Appendices of the IPC 7093 specification on Bottom Terminated Components 
which includes the use of LN2. I have not observed the use of LN2 to 
confound the testing results.

Dave



Werner Engelmaier <[log in to unmask]> 
Sent by: TechNet <[log in to unmask]>
10/22/2009 05:46 AM
Please respond to
TechNet E-Mail Forum <[log in to unmask]>; Please respond to
Werner Engelmaier <[log in to unmask]>


To
[log in to unmask]
cc

Subject
Re: [TN] [spam] RE: [TN] ENIG Issue






 Hi Inge,
Yes, I have done 'Dye & Pry.'
The 'prying' part is not easy for large components. I did it starting at 
the corners working piecemeal around the 4 sides.
LN2 is a god idea?I do not see how it would cause misleading results, 
please explain.
Werner


 

 

-----Original Message-----
From: Hernefjord Ingemar <[log in to unmask]>
To: [log in to unmask]
Sent: Thu, Oct 22, 2009 4:44 am
Subject: [TN] [spam] RE: [TN] ENIG Issue










By the way, speaking SJ issues, has anyone of you experience from Die & 
Pray 
technology, like the one described by some guys, who tested large game 
boards, 
see figur 9 and 10, dye and pry testing? It's not easy to pry so large 
BGAs. 
What kind of tools etc do you use? Myself, I had to dip the board under 
test in 
LN2 before prying off the superBGA. That's not good, the low temperature 
can 
mislead the result. 
/Inge

http://www.celestica.com/uploadedFiles/Home/PBfree_process_paper.pdf

 

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Werner Engelmaier
Sent: onsdag 21 oktober 2009 15:51
To: [log in to unmask]
Subject: Re: [TN] ENIG Issue

 Hi Vladimir,
Maybe we should simply drop the name 'Black Pad' entirely-too much baggage 
and 
confusion.
Maybe we should refer to them by their failure modes and damage 
mechanisms-solderability issues due to 'galvanic corrosion', brittle 
fracture 
due to P-enrichment, brittle fracture due to 'any other cause applicable.
Werner

 

 

-----Original Message-----
From: [log in to unmask]
To: Werner Engelmaier <[log in to unmask]>; [log in to unmask]
Sent: Wed, Oct 21, 2009 7:39 am
Subject: Re: [TN] ENIG Issue









   Werner,

Yes, I agree that there are two different phenomena BP and BF, but I can 
not 
agree on the statement that the root cause for BF(brittle fracture) is 
high P 
content. 

Regards,

Vladimir
SENTEC
11 Canadian Road, Unit 7.
Scarborough, ON M1R 5G1
Tel: (416) 899-1882
Fax: (905) 882-8812
www.sentec.ca


From:  Werner Engelmaier <[log in to unmask]>

Date: Tue, 20 Oct 2009 23:59:34 -0400
To: <[log in to unmask]>; <[log in to unmask]>
Subject: Re: [TN] ENIG Issue




 Vladimir,

Indeed you sent me that ATOTECH paper, but I have several references that 
disagree with their definition, as well as others that agree with the 
Atotech 
paper.

There seem to be (at least) 2 different 'defects' at work-one with 
hyper-galvanic corrosion of the Ni during Au-plating causing soldering 
problems, 
and another causing brittle separation due to a weakened interface cause 
by too 
much P.

Are we in agreement on this?

I do not really care what you call either of them-clearly the root cause 
is 
different in these cases and so is what needs to be done.

Clearly, what we need is for the IPC to form a committee to provide proper 

definitions and 'names.'

Werner





 





 



-----Original Message-----

From: [log in to unmask]

To: TechNet E-Mail Forum <[log in to unmask]>; Werner Engelmaier 
<[log in to unmask]>

Sent: Tue, Oct 20, 2009 11:23 pm

Subject: Re: [TN] ENIG Issue













Werner,



We've been through it several times already. As far as I know, BP was 
defined as 


a case of poor Ni-P plating with cavitation present in the layer. I think 
I sent 


you an old ATOTECH paper on the topic a while ago.



Regards,



Vladimir



SENTEC

11 Canadian Road, Unit 7.

Scarborough, ON M1R 5G1

Tel: (416) 899-1882

Fax: (905) 882-8812

www.sentec.ca





-----Original Message-----

From: Werner Engelmaier <[log in to unmask]>

Date:         Tue, 20 Oct 2009 22:57:21 

To: <[log in to unmask]>

Subject: Re: [TN] ENIG Issue



 Hi Vladimir,



Then we are not communicating.



Please explain to me what YOU mean by 'BP failure'.



When I say 'BP failure', I mean it is because too much P between the Ni 
and the 

IMC layers has weakened the bond leading to brittle separation on 
sufficient 

loading. I do not differentiate as to the cause(s) for too much P. For me 
they 

describe a damage mechanism.



You can similar appearance with too much and too little P.



Werner











 











 







-----Original Message-----



From: [log in to unmask]



To: Werner Engelmaier <[log in to unmask]>; [log in to unmask]



Sent: Tue, Oct 20, 2009 10:44 pm



Subject: Re: [TN] ENIG Issue

























   Werner,







You just confirmed what I said in my previous e-mail. You customer got 
failure 

with black appeared pads, but it wasn't BP failure. Similar appearance 
doesn't 

mean the same mechanism.







Regards,







Vladimir



SENTEC



11 Canadian Road, Unit 7.



Scarborough, ON M1R 5G1



Tel: (416) 899-1882



Fax: (905) 882-8812



www.sentec.ca















From:  Werner Engelmaier <[log in to unmask]>









Date: Tue, 20 Oct 2009 22:16:40 -0400







To: <[log in to unmask]>; <[log in to unmask]>







Subject: Re: [TN] ENIG Issue





















 Hi Vladimir,





I have one client who experienced 'Black Pad' after 9(!) soldering 
operations. 

The P-content got progressively worse; it peaked with the EDS spikes for P 
being 


as high as those for Sn.





Werner

















 

















 











-----Original Message-----





From: [log in to unmask]





To: TechNet E-Mail Forum <[log in to unmask]>; Werner Engelmaier 

<[log in to unmask]>





Sent: Tue, Oct 20, 2009 10:07 pm





Subject: Re: [TN] ENIG Issue

































Werner,















With all due respect, I don't think you are right.















Regards,















Vladimir







SENTEC







11 Canadian Road, Unit 7.







Scarborough, ON M1R 5G1







Tel: (416) 899-1882







Fax: (905) 882-8812







www.sentec.ca























-----Original Message-----







From: Werner Engelmaier <[log in to unmask]>







Date:         Tue, 20 Oct 2009 22:01:35 







To: <[log in to unmask]>







Subject: Re: [TN] ENIG Issue















 Hi George,







\While what you say in the first paragraph is correct, the second 
paragraph is 







not.







'Black Pad' is not an all-or-nothing proposition. The seeds are sown at 
the 







Ni-plating (not the Au-plating) with the P-codeposition. However, multiple 
or 







lengthy expositions to high soldering temperatures result in more Ni being 








dissolved to form IMCs leaving ever more P behind. This can create 'Black 
Pad' 







where none existed before.







Werner























 























 















-----Original Message-----







From: George Milad <[log in to unmask]>







To: [log in to unmask]







Sent: Tue, Oct 20, 2009 9:52 pm







Subject: Re: [TN] ENIG Issue























































































As always as soon as there is a solderability issue with ENIG, "Black pad" 
 







comes up. This is a problem because it does not allow for further 







investigation.  Everyone accepts since this is ENIG then it must be black 
pad.







 







If this was a black pad issue the back side should have exhibited the same 
 







problem. BP occurs during the plating of the gold on top of the Ni. BP 







cannot  differentiate one side from the other.







 







Do not accept BP as the answer and keep investigating.







 







 







Regards







George Milad







George Milad







National Accounts  Manager for Technology







Uyemura International Corp (UIC)







249 Town Line Rd 







Southington CT 06489







[log in to unmask]







Cell: (516) 901  3874















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