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January 2008

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From:
"Wenger, George M." <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Wenger, George M.
Date:
Fri, 18 Jan 2008 10:07:20 -0500
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text/plain (303 lines)
In my case it's not "THERE YOU AMERICANS GO AGAIN" it's "TH
Bev,



In my case it's not "THERE YOU AMERICANS GO AGAIN" it's "THERE YOU OLD

GUYS GO AGAIN".   After 65 years of using inches I'm having a difficult

time thinking in centimeters but I'm still can do conversions.  My

apology, I should have said "10 to 13 mils (254 to 330 microns)"





Regards,

George

George M. Wenger

Senior Principle FMA / Reliability Engineer

CommScope / Andrew Wireless Solutions

40 Technology Drive, Warren, NJ 07059 (908) 546-4531

[log in to unmask]





-----Original Message-----

From: Bev Christian [mailto:[log in to unmask]]

Sent: Friday, January 18, 2008 8:37 AM

To: TechNet E-Mail Forum; Wenger, George M.

Subject: RE: [TN] SV: [TN] SV: [TN] Solderability of Tin-Gold

Intermetallic



Sigh.  My replies below, again in BOLD.



-----Original Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Wenger, George M.

Sent: Friday, January 18, 2008 7:25 AM

To: [log in to unmask]

Subject: Re: [TN] SV: [TN] SV: [TN] Solderability of Tin-Gold

Intermetallic



I usually like to respond with answers not questions but un Bev,



I usually like to respond with answers not questions but until I

understand an issue it is hard to respond with answers.  Your question

is still vague to me.  Although you said that you are talking about

trying to make joints and not talking about joints already made, you

also said that what you are exploring is whether unusual amounts of gold

tin intermetallics on the surface of the solder balls pried off of

boards that show head in pillow did not solder because of these

intermetallics.  I view Head-in-a-Pillow solder joints as joints that

have not wet for some reason.

WELL I GUESS THIS IS A CASE OF SEMANTICS. I DON'T CONSIDER THAT A JOINT

WAS EVER MADE. If I HAD BEEN TALKING ABOUT A FRACTURE BECAUSE OF HIGH

AMOUNTS OF GOLD in A SOLDER JOINT, ok, BUT THERE WAS NO METALLURIGICAL

BOND EVER MADE IN THE CASES I AM DISCUSSING.



  If that is the case then I assume the

gold-tin intermetallics you are talking about are from the materials in

the BGA and not from the surface finish on your board.  I'm having

difficulty believing that there is enough gold in under-bump

metallization to cause a gold-tin intermetallic issues.

TRUTHFULLY SO AM I, BUT WE ARE EXPLORING ALL AVENUES.



  You indicated

that you used XRF to measure the gold concentration on samples that you

pried off.  Ingemar anticipated that you meant the part of the ball that

was soldered to the board pads.

NO. I MEANT THE BALL OF THE PART.



  However, from the way you worded your

inquiry I can't tell if you meant you looked at the board pad or the BGA

ball.

THE LATTER.



  I assumed, maybe incorrectly, that you looked at the surface of the

ball after peeling the BGA off.

CORRECT, AFTER PEELING OFF THE BGA. WE MEASURED 1.28 +/- 0.15% [Au]



  If that is the case then I would

assume that you should be able to take a non-soldered BGA and measure

the gold in a BGA ball CORRECT AND GOT 0.86 +/- 0.8% [Au]



 and then put the BGA though a reflow process without any solder paste

and re-measure the ball after reflow to see if the gold concentration

changed.

ON THE LIST OF THINGS TO DO.



  I'm assuming that you're talking about small size uBGA's with ball

diameters in the 10 to 13 mil range.

THERE YOU AMERICANS GO AGAIN. I KEEP TELLING YOU THE METRIC SYSTEM IS

NOT A COMMIE PLOT.  :) THE BALL DIAMETERS ARE 300 MICRONS.



  Since

the XRF penetration depth is typically between 1 and 2 mils you'll be

analyzing the gold in the top surface of the ball.  I assume that if you

don't see a high gold concentration in the un-reflowed solder ball that

the gold-tin intermetallics you see after the reflow process migrated to

the surface of the ball during the cooling process.  If that is the case

they probably aren't the reason for the Head-in-a-Pillow soldering

defects.

THAT'S WHAT ONE WOULD THINK. HOWEVER IF THE DIFFERENT BGA NEXT DOOR

SOLDERS PERFECTLY, YOU LOOK AT ALTERANTIVES.



MAN, THE E-MAILS ARE COMING FASTER THAN I CAN ANSWER... AND I DO HAVE A

JOB - OTHER THAN TECHNETTING.  :)



Regards,

George

George M. Wenger

CommScope / Andrew Wireless Solutions

Senior Principal FMA / Reliability Engineer 40 Technology Drive, Warren,

NJ 07059

(908) 546-4531 [Office]  (732) 309-8964 [Cell] -----Original

Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Hernefjord Ingemar

Sent: Friday, January 18, 2008 4:45 AM

To: [log in to unmask]

Subject: Re: [TN] SV: [TN] SV: [TN] Solderability of Tin-Gold

Intermetallic



Finally, you disclosed what you really wanted to know. You pried off

BGAs and found unusual amount of AuSn platetlets on the surface of the

balls. This is my opinion: If the wetting on AuSn formations is good or

not is not the first thing you ought to think of. When you say the

'surface', I anticipate that you mean the part of the ball THAT WAS

SOLDERED TO THE BOARD PADS. If THAT surface has lots of AuSn formations,

then I understand how the BGAs could be pried off = probably too much

gold from the ENIG pads = something wrong in the soldering process. IF

the solder joints were normal, you would have a real problem to get the

BGAs off the board, because healthy solder joints are enormously strong.



As to your question, whether the solder wets to AuSn intermetallics, I

think all is depending on what atmosphere you had during the IMC

formation. AuSns are, as you know, not chemical bonds, but alloys with

its gold phases and its tin phases. Now, if the tin phases are not

oxidized, then you ought to get good wetting, and vice versa. In

practice, I think that there is a high risk of AuSn oxidation, that's

why you do AuSn soldering of RF details in vacuum or inert atmosphere.



Inge



-----Original Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Bev Christian

Sent: den 17 januari 2008 16:42

To: [log in to unmask]

Subject: Re: [TN] SV: [TN] SV: [TN] Solderability of Tin-Gold

Intermetallic





Bingo!  There is the crux of it. I am not talking about joints already

made, I am talking about TRYING to MAKE joints.



I hope I don't get in trouble for this.



My original, vague question was because of - head in pillow. Inge

guessed correctly.



I don't mean to be rude, but we already have a very extensive fishbone

for this, so please don't come back with the usual reasons.  They are

being addressed, trust me.



What I am exploring is whether unusual amounts of gold tin

intermetallics on the surface of the solder balls pried off of boards

that show head in pillow did not solder because of these materials. 



Bev

RIM



-----Original Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Werner Engelmaier /*

Sent: Thursday, January 17, 2008 10:36 AM

To: [log in to unmask]

Subject: Re: [TN] SV: [TN] SV: [TN] Solderability of Tin-Gold

Intermetallic



Hi All,

We know that Cu6Sn5 is non-solderable after oxidation. However, I do not

know whether we really KNOW that it is solderable prior to that, and we

know even less about the solderability of AuSn4, Ag3Sn, or for that

matter Sn3Ni4.







Werner







**************

Start the year off right.  Easy ways to stay in shape.

    

http://body.aol.com/fitness/winter-exercise?NCID=aolcmp00300000002489



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