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May 2007

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From:
"Dehoyos, Ramon" <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Dehoyos, Ramon
Date:
Wed, 23 May 2007 10:45:16 -0400
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	Wee Mei:

	Check this one out.
	                   http://www.chemguide.co.uk/physical/phaseeqia/snpb.html
 	Ramon

-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of Brian Ellis
Sent: Wednesday, May 23, 2007 4:16 AM
To: [log in to unmask]
Subject: Re: [TN] Definition of Eutectic Solder

John is perfectly right, but if you want to research it further, the technical term of a eutectic alloy if one that goes from solidus to liquidus without passing through a phase of solid crystals in a liquid. 
Generally speaking, it occurs at a minimal temperature. For example, the Sn63Pb alloy melts at 183°C. If you have, e.g., Sn55Pb, as you heat it up, it becomes pasty at 183°C because the excess lead will not melt and will remain solid in the eutectic liquid that has melted. Heat it further and it will not attain liquidus until about 205°C. The Sn96.5Ag alloy is eutectic at 221°C (pure tin melts at 232°C). Many binary alloys have eutectic compositions. I don't believe ternary or higher alloys have true eutectic compositions, although they may pass from solidus to liquidus over a very short temperature range of, say, 1°C or less, making them behave as if they are eutectic, but that may be hair-splitting. No doubt Werner or others with a better knowledge of metallurgy than I will jump down my throat. The reason why near-eutectic compositions are desirable is that even a tiny mechanical shock to the assembly when it is between liquidus and solidus during cooling will derange the orderly crystal formation and thus weaken the joint.

Brian

Lum Wee Mei wrote:
> Hello,
>  
> What is actually eutectic solder? All along I have this impression that when we talk of eutectic solder, it is refer to Sn63. However, yesterday, I attended a course and was told that Sn96 (4% silver) is also eutectic. Can someone enlightenment me?
>  
> Thanks and regards,
> Wee Mei
> 
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