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May 2007

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Subject:
From:
Brian Ellis <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Brian Ellis <[log in to unmask]>
Date:
Wed, 23 May 2007 11:15:43 +0300
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John is perfectly right, but if you want to research it further, the 
technical term of a eutectic alloy if one that goes from solidus to 
liquidus without passing through a phase of solid crystals in a liquid. 
Generally speaking, it occurs at a minimal temperature. For example, the 
Sn63Pb alloy melts at 183°C. If you have, e.g., Sn55Pb, as you heat it 
up, it becomes pasty at 183°C because the excess lead will not melt and 
will remain solid in the eutectic liquid that has melted. Heat it 
further and it will not attain liquidus until about 205°C. The Sn96.5Ag 
alloy is eutectic at 221°C (pure tin melts at 232°C). Many binary alloys 
have eutectic compositions. I don't believe ternary or higher alloys 
have true eutectic compositions, although they may pass from solidus to 
liquidus over a very short temperature range of, say, 1°C or less, 
making them behave as if they are eutectic, but that may be 
hair-splitting. No doubt Werner or others with a better knowledge of 
metallurgy than I will jump down my throat. The reason why near-eutectic 
compositions are desirable is that even a tiny mechanical shock to the 
assembly when it is between liquidus and solidus during cooling will 
derange the orderly crystal formation and thus weaken the joint.

Brian

Lum Wee Mei wrote:
> Hello,
>  
> What is actually eutectic solder? All along I have this impression that when we talk of eutectic solder, it is refer to Sn63. However, yesterday, I attended a course and was told that Sn96 (4% silver) is also eutectic. Can someone enlightenment me?
>  
> Thanks and regards,
> Wee Mei
> 
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