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October 2006

Leadfree@IPC.ORG

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Subject:
From:
"James, Chris" <[log in to unmask]>
Reply To:
(Leadfree Electronics Assembly Forum)
Date:
Mon, 30 Oct 2006 13:40:47 -0000
Content-Type:
text/plain
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text/plain (168 lines)
Per homogeneous substance/item - so every solder joint must comply in

its own right - if one solder joint is above the limit level then the

whole pwb fails.



Regards,

Chris

 



-----Original Message-----

From: Leadfree [mailto:[log in to unmask]] On Behalf Of Stadem, Richard D.

Sent: 30 October 2006 13:36

To: [log in to unmask]

Subject: Re: [LF] Leadfree assembly contaminated?



Does the .1% Pb limit apply to any single point on the pwb, or can it be

an average of readings from several different points? 



-----Original Message-----

From: Leadfree [mailto:[log in to unmask]] On Behalf Of Timothy McGrady

Sent: Sunday, October 29, 2006 7:57 AM

To: [log in to unmask]

Subject: Re: [LF] Leadfree assembly contaminated?



Gen:



I agee with Ioan.  XRF mesurements of in situ solders are not easy and

not very accurate, considering that in your case any Pb would probably

not be uniformly distributed.  However, knowing what the European

enforcement bodies are likely to do, if you have the solder tested via

XRF and the Pb concentration is low - not just below 0.1%, but anywhere

near 0.1% - they are unlikely to challenge your claim that the product

is compliant.  If they saw 40% lead with an XRF, they would likely

proceed to quantitative analysis by ICP-AES to confirm the high lead

reading.  Some enforcement authorities might be more agressive and go

straight to quantitative analysis, but they will have to be quite sure

of themselves if they want to prosecute someone for Pb values a little

higher than 0.1%, particularly if you did your due diligence and had

your reflowed solder checked and can document that with a test

certificate. The only problem with having an instrument manufacturer do

the test is that they likely do not qualify as an independent test lab

and cannot give a certificate that would hold the same weight as one

from a laboratory.



Tim McGrady

----- Original Message -----

From: "Tempea, Ioan" <[log in to unmask]>

To: <[log in to unmask]>

Sent: Saturday, October 28, 2006 6:38 PM

Subject: Re: [LF] Leadfree assembly contaminated?





Gen,



how could you do that? I bet nobody else did it, including ourselves.



As per our experience and XRF measurements you should be OK if the

wicking of the pads is very very good. For a very well wicked pad, no

spikes or little islands, just a flat pad left after the cleaning, we

measured about 3 to 4% Pb in the coating layer. Imagine adding a

comparatively huge volume of lead-free solder on top of it, you end up

with the Pb diluted well below the 0.1% treshold.



Of course, you don't kow how well your CM did the cleaning, but if you

ask them to change the IC again, the Pb will surely go away. Now, how

confident are you in your PCB quality to do that, only you can answer.



We have an XRF and I tell you from my painful experience that measuring

in electronics using this technology is not a piece of cake. Therefore,

if you want to qualify the boards, I suggest you contacted XRF machines

manufacturers, tell them you are interested in buying one and have them

check the boards for you, for a test. Not too orthodox, but life is not

always fair, is it?



Good luck,



Ioan



-----Original Message-----

From: Leadfree

To: [log in to unmask]

Sent: 27/10/2006 4:20 PM

Subject: [LF] Leadfree assembly contaminated?



Our CM placed and reflowed an IC with SnPb leads on a leadfree assembly.

Then they removed it and replaced it with the leadfree part.



  Is this assembly contaminated with Pb to a level that would be a

failure under RoHS?  We have several boards in limbo.

  Does anyone know of a lab capable of determining this, in Canada?



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