Chris,
NPL paper shows that mixed solders (LF mixed with SnPb) provide better reliability than SnPb alone. This will happen when there is reflow of both solders.
The question being asked, however, is different. Some folks want to use a LF solder ball package in SnPb reflow profile. LF will not reflow in 225 - 235 C range. Visually joint may look OK because SnPb has reflowed covserin the pad and LF solder ball. LF solder ball, however, has not reflowed. That produces a weak unreliable joint.
One may have to use rework type approach as shown by NPL data where the reflow of LF solder ball is assured by using the right thermal profile.
__________________________
pratap singh
tel./fax 512-255-6820
email:[log in to unmask]
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