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March 2004

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Subject:
From:
Mike Fenner <[log in to unmask]>
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Date:
Fri, 19 Mar 2004 09:10:22 -0000
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Very neat Bill thanks.
May I suggest a refinement, or at least a flag, to test 3 the heat gun?
If the residues are partially removed rosin or resin, which can also
have a white or off white appearance, the heat gun will melt it to a
translucent or clear appearance. Visually this would be similar to the
powder disappearing. So the refinement would be to either know the
generic flux type in use, or carry out an additional inspection, or pick
at the area to see if the resides flake off.

Regards

Mike Fenner
Indium Corporation

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-----Original Message-----
From: TechNet [mailto:[log in to unmask]] On Behalf Of [log in to unmask]
Sent: 19 March 2004 05:33
To: [log in to unmask]
Subject: Re: [TN] White residue


I will summarize some points re your problem which hopefully will make
it
easier for others to add their thoughts-
1. The residue- while there are many causes to white, tan, yellow, gray
residues; the most likely cause in your case would be the insoluble
activator
residues from your no clean flux. As Brian points out, these residues
are meant to
be left behind, and their presence is not supposed to be harmful. Most
likely
they are a dibasic acid, generally adipic acid, although succinnic,
tartaric
and malic acids have also been used. Check in a Chemical Handbook and
you will
find that adipic acid is not really very soluble in anything, which
gives some
insight on why it remains on the completed assembly.
2. Quick identification of the (flux) residue-- if it is a dibasic acid,
dip
a Q-tip in 0.1 N NaOH, touch it to the residue, rinse with water, rinse
with
IPA, and blow dry with dry, oil-free compressed air. Best to do this on
a scrap
board that is run through the soldering process so it can be discarded
afterwards. If the spot is now clean, contaminant is most likely dibasic
acid.
3. Quick identification of the (solder mask) residue- if it is the white
powder fumed silica used to thicken liquid solder masks, you will often
see it
appear as Brian has noted. If the solder mask is undercured, any
cleaning step
may strip off part of the green solder mask, exposing the white
thickener powder
(typical trade name is 'Cab-O-Sil"). Heat the white area with a heat
gun. If
the residue is the Cab-O-Sil, the heat softened solder mask will allow
the
Cab-O-Sil to sink back into the green solder mask. Residue disappears,
problem is
insufficient UV cure during solder mask processing. [Quick, cheap tests
are
great !]
4. A-610 residue allowance- Most folks using 610 follow the rules that
visible residues are not acceptable. Arguing with customers that the
residue is x or
y or z normally tends to be an uphill battle, especially when the
customer
asks you to accept the liability that the residue will be x every
time... You
will sleep much easier if you can find a way to eliminate the residue,
even if a
cleaning step is required.
5. Many US companies offer cleaning agents that will quickly remove no
clean
flux residues. Certain of these companies even offer contract cleaning
services, where they maintain a cleaning centre staffed by experts with
all different
types and sizes of cleaning equipment and appropriate cleaning agents,
plus
testing equipment. They will accept the problem PWAs, clean them, test
them and
return them to you via express shipping. In the long run, this is much
more
economical than maintaining cleaning experts and processes in house.

Let me know if clarification or elaboration of any of these points is
needed.

Bill Kenyon
Global Centre Consulting
3336 Birmingham Drive
Fort Collins, CO   80526   USA
Tel: 970.207.9586     Cell: 302.377.4272

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