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Date: | Wed, 22 May 96 18:49:29 CST |
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Well, here's my two cents. To answer your question - Yes.
ANY dissimilarity of metals will cause some degree of
corrosion through the difference of electronegativity.
You can't get away from it. There's another thing that
happens, more exotic, based on Fick's Law for the physical
migration of one metal into another in a way similar to the
way two gases mix. Alright. Big deal. So what?
1. Any electronegativity of elements chart will show
0.6 volts for Nickel and Gold. Nickel is the more
anodic and gold is the more cathodic.
2. There are two kinds of compatibility of metals charts
that I've found.
One type used by UL places an upper limit of 0.6 volts
electronegativity between dissimilar metal combinations.
The rule for this type of chart is "stay with a
combination equal to or less than 0.6 volts."
Another, places the dissimilar metals into groups.
The groups divide the various metals by allowing no more
than 0.25 volts as the upper limit in difference with
electronegativity. The rule for this chart is "stay
within the group."
Unfortunately, the UL chart based on 0.6 volts says that
it's OK to mix nickel and gold. The other chart that
groups the metals says that it's NOT.
I would suggest avoiding it. I'm sure alot of other people
have good input on this.
______________________________ Reply Separator _________________________________
Subject: assy:compatibility gold vs. tin/lead
Author: [log in to unmask] at internet-mail
Date: 5/22/96 11:12 AM
We have instances where tin/lead coated pins are inserted into gold plated
sockets, etc. Components even have gold/tin-lead or gold/tin interfaces,
such as an IC socket with a gold contact with a tin sleeve. Mil-Std-889B
indicates gold as being incompatible with tin or tin/lead. Has anyone
looked into this issue and is there a potential for corrosion formation and
associated problems? Again, I just referring to mechanical contact ( not
soldering ).
Thanks,
Jack Tippit
Wilcox Electric
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