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September 2009

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From:
"Wenger, George M." <[log in to unmask]>
Reply To:
TechNet E-Mail Forum <[log in to unmask]>, Wenger, George M.
Date:
Tue, 22 Sep 2009 15:21:18 -0400
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Peter is having problems with immersion TIN not immersion S
Lee,



Peter is having problems with immersion TIN not immersion SILVER



Regards,

George

George M. Wenger

Andrew Solutions

Senior Principal FMA / Reliability Engineer

40 Technology Drive, Warren, NJ 07059

(908) 546-4531 [Office]  (732) 309-8964 [Cell]

[log in to unmask]

 

-----Original Message-----

From: TechNet [mailto:[log in to unmask]] On Behalf Of Lee parker

Sent: Tuesday, September 22, 2009 3:03 PM

To: [log in to unmask]

Subject: Re: [TN] Imm Sn soldering issue.



Peter you mentioned that the defects are normally on the second side. I

was also wondering if the defects are usually associated with the same

features. If so you may have problems other than the immersion silver

surface. Issues I have uncovered are soldermask residues and soldering

fixtures (if you are using fixtures) that prevent contact of the board

and the solder. I suggest that the next time this occurs you process a

bare board with no no soldermask or fixturing and see if you get the

same result. Quite often I do not.



Best regards

Lee

J. L. Parker Ph. D.

JLP Consultants LLC

804 779 3389

  ----- Original Message ----- 

  From: Peter Barton<mailto:[log in to unmask]> 

  To: [log in to unmask]<mailto:[log in to unmask]> 

  Sent: Tuesday, September 22, 2009 12:33 PM

  Subject: [TN] Imm Sn soldering issue.





  Dear Technetters,



  Hopefully there is someone out there who can help me understand a very

specific issue we have using PCB's plated with Imm Sn. namely,

non-wetting of solder to some lands on the second side of population

after reflow. We have an understanding of this surface finish with

respect to the assembly processes. We are careful how we handle the

unpopulated PCB's, the PCB's are shipped directly to the line and are

only removed from the manufacturer's packaging at the point of use. They

are not pre-baked and are subjected to 2 relatively benign reflow

cycles.



  We only ever see the issue on the second side. It occurs on various

component types. When it does occur the solder deposited at the printing

stage is reflowed and is attached to the component termination,

favouring this as more wettable than the PCB land. The problem does not

always occur. The assembly is populated in 2 up panels and we have

examples where one panel has soldered joints across the piece, whilst

the other PCB in the same panel exhibits non wetting in some areas.



  The assembly has been profiled with a good distribution of

thermocouples on a sample assembly to confirm a low delta T and the

profile itself is right at the centre of the paste manufacturer's

recommendations. We like to have a good process window.



  I am aware that the 2 possible reasons for this condition are (a)

thermal degradation of the finish and (b) possible plating quality

issues.



  We have dismissed excessive thermal input as these have only been

subjected to 2 non-RoHS thermal cycles and the PCB's are fresh from the

manufacturer. Peak temperatures are only around the 227 deg. C mark. The

Sn thickness specification is 0.8 - 1.2 uM. The applied thickness has

been measured using XRF as a process control and averages 1.0 uM. I am

aware that XRF is only a guide as it cannot segregate out 'available'

pure Sn from Sn/Cu intermetallics.



  We have had an independent lab analysis conducted and example lands

where this condition is seen are shown to have very little or no

remaining Sn at the surface, the majority being Sn/Cu intermetallics.

Other unpopulated plated areas have also been subjected to SEM and EDX

for comparison and exhibit what is described as 'islands' of Sn in a sea

of Cu/Sn intermetallics.



  We have not had 'virgin' PCB's analysed yet for comparison as it is

costly and we are not sure if we would pick the correct example to look

at - it could be a good one.



  For the PCB experts out there out there I have a couple of questions:



  1. If the application of Sn is a displacement reaction with the

underlying Cu is there any way that there can be less Sn on some surface

areas than others?



  2. Are there other reasons that there could be variation in Sn

deposits or could lead to the 'islands' of Sn as described by our lab

that is seen after thermal processing?



  3. Are we missing anything else?



  Any questions please feel free to ask - this is causing me the biggest

headache going.



  Peter Barton

  Senior Process Engineer

  ACW Technology Ltd

  Dinas Isaf West

  Tonypandy

  Mid Glamorgan

  CF40 1XX



  Tel: 01443 425275 (direct)

  Fax 02380 484882

  [log in to unmask]<mailto:[log in to unmask]>



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